We present a detailed analysis of the role of the magnetic dipole-dipole interaction in
cold and ultracold collisions. We focus on collisions between magnetically trapped NH
molecules, but the theory is general for any two paramagnetic species for which the
electronic spin and its space-fixed projection are (approximately) good quantum numbers.
It is shown that dipolar spin relaxation is directly associated with magnetic-dipole
induced avoided crossings that occur between different adiabatic potential curves. For a
given collision energy and magnetic field strength, the cross-section contributions from
different scattering channels depend strongly on whether or not the corresponding avoided
crossings are energetically accessible. We find that the crossings become lower in energy
as the magnetic field decreases, so that higher partial-wave scattering becomes
increasingly important below a certain magnetic field strength. In
addition, we derive analytical cross-section expressions for dipolar spin relaxation based
on the Born approximation and distorted-wave Born approximation. The validity regions of
these analytical expressions are determined by comparison with the NH + NH cross sections
obtained from full coupled-channel calculations. We find that the Born approximation is
accurate over a wide range of energies and field strengths, but breaks down at high
energies and high magnetic fields. The analytical distorted-wave Born approximation gives
more accurate results in the case of s-wave scattering, but shows some
significant discrepancies for the higher partial-wave channels. We thus conclude that the
Born approximation gives generally more meaningful results than the distorted-wave Born
approximation at the collision energies and fields considered in this work.