Mn
2+Sb
2S
4, a monoclinic dimorph of clerite, and benavidesite (Mn
2+Pb
4Sb
6S
14) show well-individualized single chains of manganese atoms in octahedral coordination. Their magnetic structures are presented
and compared with those of iron derivatives, berthierite (Fe
2+Sb
2S
4) and jamesonite (Fe
2+Pb
4Sb
6S
14). Within chains, interactions are antiferromagnetic. Like berthierite, MnSb
2S
4 shows a spiral magnetic structure with an incommensurate 1D propagation vector [0, 0.369, 0], unchanged with temperature.
In berthierite, the interactions between identical chains are antiferromagnetic, whereas in MnSb
2S
4 interactions between chains are ferromagnetic along
c-axis. Below 6 K, jamesonite and benavidesite have commensurate magnetic structures with the same propagation vector [0.5, 0, 0]:
jamesonite is a canted ferromagnet and iron magnetic moments are mainly oriented along the
a-axis, whereas for benavidesite, no angle of canting is detected, and manganese magnetic moments are oriented along
b-axis. Below 30 K, for both compounds, one-dimensional magnetic ordering or correlations are visible in the neutron diagrams
and persist down to 1.4 K.
Keywords Manganese - Sulfosalt - Benavidesite - Magnetic properties - Neutron diffraction - Magnetic structure