Radon is a significant component of the groundwaters that discharge in the springs of Szczawno Zdrój and are recognized as medicinal. However, among the five exploited springs adjoining each other, it is only in Marta Spring that radon occurs in large concentrations (up to 325.6 Bq/dm³). Therefore, the authors have made an attempt to describe and clarify this fact. They found out from their own research and archival data that ²²²Rn dissolves in the waters of Marta Spring after acidulous waters of deep circulation have mixed with poorly mineralized shallow waters in their outflow zone. The genesis of the gas is determined by the content of its parent nuclide, ²²⁶Ra, in the sandstones in the vicinity of the intake. The volume of the rocks providing radon to the waters of this intake has been estimated at several hundred cubic metres. No seasonal fluctuations in radon concentration have been observed and ²²²Rn concentration changes do not seem to be influenced by changes in the concentration of other chemical components of the waters or by the discharge of the intake. The process of dissolving ²²²Rn in the medicinal groundwaters of Marta Spring is the last, the shortest, and the most local of the processes that form the chemical composition and the physical properties of these waters.