Optical characteristics of the HfO
2 − x
N
x
and TiO
2 − x
N
x
films obtained by reactive ion beam sputtering have been investigated by spectral ellipsometry. The chemical composition
of the films was determined using X-ray photoelectron spectroscopy. The nitrogen content in the oxynitride films (determined
by the N
2/O
2 ratio in the gas mixture during synthesis) reached ≈9 at % for TiO
2 − x
N
x
and ≈ 6 at % for HfO
2 − x
N
x
. It is found that the dispersion relations
n(λ) and
k(λ) for the TiO
2 − x
N
x
films change from those characteristic of titanium dioxide to those typical of titanium nitride with an increase in the nitrogen
content from 0 to ≈9 at %. The optical parameters of the HfO
2 − x
N
x
films depend weakly on the nitrogen content in the range 0–6 at %.
PACS numbers 78.20.-e
Original Russian Text © V.V. Atuchin, V.N. Kruchinin, A.V. Kalinkin, V.Sh. Aliev, S.V. Rykhlitskiĭ, V.A. Shvets, E.V. Spesivtsev,
2009, published in Optika i Spektroskopiya, 2009, Vol. 106, No. 1, pp. 77–82.