The mechanical properties of four different types of geopolymers, but of the same composition (Na/Al ≈ 1, Si/Al ≈ 2 molar
ratio), made using a combination of precursors, were determined. The four types were: (i) sodium aluminate (NaAlO
2/NaOH solution), Ludox (colloidal SiO
2 solution) and metakaolin (MK), (SAGP), (ii) NaOH, fumed silica and MK (FSGP), (iii) Ludox, NaOH and MK (LGP) and (iv) commercial
sodium silicate and MK (SGP). The highest crushing strength (CCS) value obtained was for SGP (70 MPa) and the lowest value
was for SAGP (16 MPa). The highest modulus of rupture (MOR) value obtained was for LGP (9 MPa) and the lowest value was for
SAGP (3 MPa). The fracture toughness (K
1c) and Young’s modulus (E) showed the same trend. The effect of adding sand (40 wt%) on their mechanical properties was also
determined. The K
1c values increased up to 65% and E values increased up to 80% compared to samples free of sand. However, CCS and MOR values
did not change much and gave mixed results. Overall, porosity is found to be the chief microstructural variable limiting the
mechanical properties of the geopolymers. The properties of the geopolymers are compared with those of ordinary Portland cement.