Volume 167, Numbers 1-3, 869-873, DOI: 10.1007/s10751-006-9371-9

Automated Mössbauer spectroscopy in the field and monitoring of fougerite

D. Rodionov, G. Klingelhöfer, B. Bernhardt, C. Schröder, M. Blumers, S. Kane, F. Trolard, G. Bourrie and J.-M. R. Génin

From the issue entitled "Proceedings of the 28th International Conference on the Applications of the Mössbauer Effect (ICAME 2005) held in Montpellier, France, 4-9 September 2005 Part III / V"

View Related Documents

Abstract

A special experimental setup for in-field applications was developed at Mainz. It incorporates hardware for automated positioning of the Mössbauer sensor head, a Plexiglas tube, and a modified version of the space proven Miniaturized Mössbauer Spectrometer MIMOS II (Klingelhöfer et al., Science, 306:1740–1745, 2004; Klingelhöfer et al., J. Geophys. Res., 108(E12):8067, 2003; Klingelhöfer et al., Hyperfine Interact. 144/145:371–379, 2002; Génin et al., Solid State Sci., 7:545–572, 2005). MIMOS operates in backscattering geometry, thus no sample preparation is required. Also dedicated software for running measurement sequences (e.g., different depth positions at different times etc.) was developed. The setup can work autonomously up to several weeks in the field. Preliminary results confirm that fougerite mineral found in hydromorphic soils is FeII–III hydroxycarbonate green rust.

Key words  methodology - hydromorphic soil - MIMOS II - environment - fougerite - green rust

Fulltext Preview

Image of the first page of the fulltext document