A special experimental setup for in-field applications was developed at Mainz. It incorporates hardware for automated positioning
of the Mössbauer sensor head, a Plexiglas tube, and a modified version of the space proven Miniaturized Mössbauer Spectrometer
MIMOS II (Klingelhöfer et al.,
Science, 306:1740–1745, 2004; Klingelhöfer et al.,
J. Geophys. Res., 108(E12):8067, 2003; Klingelhöfer et al.,
Hyperfine Interact. 144/145:371–379, 2002; Génin et al.,
Solid State Sci., 7:545–572, 2005). MIMOS operates in backscattering geometry, thus no sample preparation is required. Also dedicated software
for running measurement sequences (e.g., different depth positions at different times etc.) was developed. The setup can work
autonomously up to several weeks in the field. Preliminary results confirm that fougerite mineral found in hydromorphic soils
is Fe
II–III hydroxycarbonate green rust.
Key words methodology - hydromorphic soil - MIMOS II - environment - fougerite - green rust