In the Noril’sk ore field, maucherite, Ni₁₁As₈, occurs in magmatic pentlandite-pyrrhotite-chalcopyrite ores transformed into pyrite-millerite-chalcopyrite and millerite-bornite ores under conditions of prehnite-pumplellyite and zeolite facies of metamorphism. Maucherite spatially associated with aggregates of Pd and Pt minerals, probably, as a pseudomorph after mayakite, PdNiAs, contains up to 1.5 wt % Pd. Maucherite is relatively abundant in metamorphic-hydrothermal apophyllite-anhydrite-calcite veins hosted in metaore. In these veins, maucherite occurs as finely split and long-prismatic crystals, their intergrowths, and as a constituent of complexly zoned antimonide-sulfoarsenide-arsenide nodules. Maucherite from veins contains up to 0.6 wt % S and Sb, whereas Pd, Pt, and Au are below the detection limit of an electron microprobe.