A novel linear ion trap mass analyzer was developed using just four elongated planar electrodes, mounted in parallel, and
employing an RF potential for ion trapping in the radial and axial directions. Mass analysis was achieved using the mass-selective
instability scan with ion ejection in the radial direction. The performance of this new device was characterized in comparison
with the 6-electrode rectilinear ion trap (RIT) from which it is derived. The 4-electrode trap gives optimum performance in
an asymmetric geometry, just like the original optimized 6-electrode RIT. The strong RF fringing fields at the ends of the
RF rods account for axial ion trapping without use of extra electrodes or an axial DC voltage. Field calculations and simulations
have been carried out to study the trapping potential inside RITs with various configurations. Demonstrated capabilities include
analysis of externally injected ions with mass resolution in excess of 1000 and a mass/charge range of 650 Th as well as tandem
mass spectrometry capabilities. The geometric simplicity and performance characteristics of the 4-electrode RIT make it particularly
attractive in the development of next generation miniaturized mass spectrometers.
Published online February 28, 2006