This paper discusses the mechanisms that can contribute to the enhanced longitudinal piezoelectric effect along nonpolar directions
in perovskite crystals, such as BaTiO
3, PbTiO
3, KNbO
3, Pb(Mg
1/3Nb
2/3)O
3-PbTiO
3 and Pb(Zn
1/2Nb
2/3)O
3-PbTiO
3. Piezoelectric anisotropy is discussed in relation to temperature induced phase transitions, compositional variation in solid
solutions with morphotropic phase boundaries, applied electric fields, the domain wall structure and domain wall displacement.