Volume 47, Number 7, 1374-1378, DOI: 10.1007/BF02495569

The influence of additives to the Speier catalyst on hydrosilylation of functionalized alkenes

E. A. Chernyshev, Z. V. Belyakova, L. K. Knyazeva, M. G. Pomerantseva and L. A. Efimova

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Abstract

Hydrosilylation of several unsaturated compounds with triethoxysilane in the presence of the Speier catalyst with various additives influencing the reaction rate and selectivity was studied. The mechanism of hydrosilylation is discussed.

Key words  hydrosilylation - reduction - catalysis - catalysts - selectivity - regioselectivity - mechanism

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1413–1417, July, 1998.

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