Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development

Fangdong Yin, Daniel Grosjean and John H. Seinfeld

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Abstract

Detailed theoretical (Part I, this article) and experimental (Part II) investigations are presented for the mechanism of the atmospheric photooxidation of dimethyl sulfide (CH₃SCH₃) and dimethyl disulfide (CH₃SSCH₃). In this paper, comprehensive mechanisms for the atmospheric chemistry of CH₃SCH₃ and CH₃SSCH₃ are developed based on fundamental considerations of all available kinetic and mechanistic information.

Key words Dimethyl sulfide - dimethyl disulfide - photooxidation mechanism

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Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development

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Abstract

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