The influence of radiation damage on a number of lattice vibration parameters in two SiO
2 modifications was investigated using IR reflectance spectroscopy. The radiation kinetics of changes in spectral characteristics
of SiO
2 fundamental vibrations in crystalline and glassy states were determined. The reflectivity coefficient and the frequency of
degenerate vibrations as functions of dose showed minima, the locations of which were governed by the type of sample. At high
neutron irradiation doses (10
21 cm
−2), certain characteristics of the bands had the same values for both modified materials. Features of the radiation kinetics
of sample dynamic parameters were determined. It was deduced that the specific character of the observed radiation-induced
changes in spectral and dynamic parameters of vibrations near degenerate modes was due to both the accumulation of radiation
damage and a change in the force field surrounding bridging bonds, which is related to a change in the SiO
2 structure.
Key words IR spectrum - antisymmetric vibrations - dynamic parameters - neutron flux - radiation kinetics - structure rearrangement
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 354–358, May–June, 2008.