The behaviour of platinum-group elements (PGE) in the exogenic cycle was examined in profiles of oxidized Main Sulfide Zone (MSZ) ores, in which the general metal distribution patterns of the pristine MSZ are grossly preserved. However, at similar Pt grades, significant proportions of Pd have been lost from the system. This indicates that Pd is more mobile than Pt and is dispersed in the supergene environment. Sperrylite and cooperite/braggite are stable in the oxidized MSZ. In contrast, the (Pt,Pd)-bismuthotellurides, common in pristine MSZ ores, have disintegrated, and ill-defined (Pt,Pd)-oxides or (Pt,Pd)-hydroxides have formed. The assemblage of detrital PGM present in the Makwiro River close to the Hartley Platinum Mine indicates further mineralogical changes. Sperrylite largely remains stable whereas most cooperite/braggite grains have been partly altered or completely destroyed. Grains of Pt-Fe alloy are ubiquitous in the alluvial sediments. Most likely, these grains are neo-formations that formed either from pre-existing, unstable PGM or via a solution stage under low-temperature conditions.