Volume 19, Number 2, 213-218, DOI: 10.1007/BF00853359

New organic reagents for the photometric determination of Ba, Sr, Ca, and SO42−

T. V. Petrova, I. Khakimkhodzhaev and S. B. Savvin

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Abstract

1.  Eleven bis-azo derivatives of chromotropic acid, containing a COOH group in the o-position to the azo group in one of the benzene rings and NO2, SO3H, AsO3H2, COOH, CH3, Cl, and OCH3 groups in the m- and p-position to the azo group, were studied as reagents for Ca, Sr, Ba, and sulfates.
2.  Most of the compounds considered are highly sensitive reagents for Sr, Ba, and sulfates.
3.  The possibility of a photometric determination of Sr, Ba, and SO 4 2– with a reagent containing a NO2 group in the p-position to the azo group, i.e., carboxynitrazo, was demonstrated.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 259–265, February, 1970.

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