Electronic spectral studies of some lanthanoids [(viz. Pr(III), Nd(III), Sm(III), Eu(III), Dy(III), Er(III) and Tm(III)] in
aminopolycarboxylate (viz. IMDA, NTA, HEDTA, EDTA, CDTA and DTPA) environment have been undertaken with a view to evaluate
the oscillator strengths (
f
JO), Judd-Ofelt parameters (τ
λ), inter-electronic repulsion Racah parameters (
∂E
k) and nephelauxetic ratios (
∂E
3/
∂E
1). The parameters have been evaluated for the entire
pH range (
pH 2–9) with intervals of 0.5 in order to study the dependence of oscillator strengths on
pH values. The extent of covalency (via parameter
τ
2) and symmetry (via parameters
τ
4 and
τ
6) in the metal-ligand interaction have been estimated with the help of τ
λ parameters. The values of oscillator strengths and Judd-Ofelt parameters have been discussed in the light of coordination
number of lanthanoid metal ions, denticity and basicity of the ligands. The metal-ligand bonding pattern has been studied
in the light of changes in Racah parameters and the nephelauxetic ratio. The oscillator strength values for some specific
hypersensitive transitions and for the transition where
U
λ values are significantly large have been studied as a function of ground term
L and
J quantum numbers of the lanthanoids.
Keywords Lanthanoids - electronic spectra - nephelauxetic parameters - aminopolycarboxylates.