The expediency of refining some basic concepts of the common theory of interaction between an electromagnetic field and a
substance using a quasi-classical model for the phenomena of absorption and emission of energy and Raman scattering (RS) is
considered. The use of the time-dependent Schrodinger equation for obtaining the transition probability constants is discussed.
A new model that describes the intensities of the RS lines and involves the explicit introduction of the perturbation operator
for the RS spectrum is proposed.
Key words Raman scattering - time-dependent Schrödinger equation
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 309–318, May–June, 2008.