After preliminary mechanical activation a mixture of solid chromium(III) chloride and sodium acetylacetonate becomes capable of reacting to form chromium acetylacetonate. The reaction may be carried out in the mode of a self-propagating process.
Key words self-propagating synthesis - mechanical activation - complex compounds - chromium acetylacetonate
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1150–1152, June, 1995.
The work was carried out as a part of the Project No. 1-164
Mechanochemical Synthesis of Complex Compounds
of State Scientific and Technical Program
Ecologically Safe Processes in Chemistry and Chemical Technology
under financial support of The Ministry of Science of the Russian Federation and of the Russian Foundation for Basic Research (Project No. 95-03-08244a).