Abstract We discuss the distribution of dust and atomic hydrogen in and around a small dark cloud near

Ophiuchi. Although the obscuration reaches values as high as 8 magnitudes, the values of
N
H derived inside the cloud do not differ markedly from those found at nearby, less obscured points. At low values of the obscuration, dust and hydrogen isophotes show satisfactory agreement, i.e.,
N
H increases with
N
G. However, we find that
N
H starts decreasing for sufficiently large values of
N
G. In the entire range of optical extinctions investigated our observations are satisfied by an expression of the type
N
H=
AN
G exp (-
BN
G). Interpretation of this relationship suggests that an appreciable part of the hydrogen has been converted to molecular form inside the cloud. A tentative method for calculating the time elapsed since the conversion process began is proposed.