We consider a mixed covolume method for a system of first order partial differential equations resulting from the mixed formulation of a general self-adjoint elliptic problem with a variable full diffusion tensor. The system can be used to model the transport of a contaminant carried by a flow. We use the lowest order Raviart-Thomas mixed finite element space. We show the first order convergence in L ² norm and the superconvergence in certain discrete norms both for the pressure and velocity. Finally some numerical examples illustrating the error behavior of the scheme are provided.