Volume 37, Number 3, 237-243, DOI: 10.1023/A:1010494226972

Mechanism of Local Activation of Copper in the Presence of Chloride and Sulfate Ions at Elevated Temperature and Heat Transfer

S. A. Kaluzhina and I. V. Kobanenko

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Abstract

The influence of temperature, positive heat flux, and activating ions on the kinetics of the local activation of copper in borate solutions on an experimental setup with a contact-heated rotating disk electrode is discussed. It is shown that the metal resistance to local activation substantially depends on the thermal conditions; their effect is comparable with that of an activator. The possibility of describing the mechanism of local activation in terms of currently prevalent theories of pitting initiation is analyzed.

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