We present a rigorous derivation of the formulae of Dirac-Bloch and Wigner-Seitz for the quantum mechanical exchange energy
and the ‘exchange hole’ of the free electron gas. More precisely we establish that for arbitrary determinantal ground states
of the underlying finite system of
N free electrons in a box, subject to periodic or zero boundary conditions, the formulae are accurate to order
(per electron) and
respectively.
Received: 22 March 1996/Accepted: 20 August 1996