In the crystal structures of the minerals edoylerite, deanesmithite, and wattersite and in the structures of the compounds HgCrO
4, Hg
3O
2CrO
4 (analog of the mineral schuetteite), and Pb
2HgO
2CrO
4, there are atomic groups or fragments linked by relatively strong (covalent) bonds. The anion fragments represented by CrO
4 tetrahedra are condensed into pairs and chains, in which adjacent tetrahedra are related by symmetry centers. The cation fragments form various patterns from zigzag ribbons of [Hg
4S
4] rings to ribbons and frameworks with [Hg
6O
2]
r-octahedra, [Hg
2CrO] and [Pb
2HgO] triangles, and [Hg
6Cr
2O
4] (stella quadrangula) groups. The symmetry of the fragments and their assemblies is analyzed. Analysis of the reference crystal-forming planes has revealed cation sublattices (close to the
F-cubic sublattice in two cases), determining the typical features of the structures.
crystal chemistry of mercury chromates - 2[CrO4] and [CrO4]
anion fragments - oxo-centered [Hg4O] tetrahedra - [Hg6O2] cationic r-octahedra - [Hg6Cr2O4] fragment (stella quadrangula)
Original Russian Text Copyright © 2004 by S. V. Borisov, S. A. Magarill, and N. V. Pervukhina
Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 471–479, May–June, 2004.