The error structure of radar measurements should be accurately known in order to provide reliable estimates for a number of quantitative meteorological applications, from rainfall rate estimation to cloud microphysics. The aim of this paper is to give a detailed characterization of Z _H and Z _DR measurements obtained by the weather radar of Fossalon di Grado (Gorizia, Italy). Vertical-looking observations are used to determine the system bias on differential reflectivity and to estimate the measurement error on both Z _H and Z _DR in the rain medium. It is estimated that no bias is affecting Z _DR and the accuracy of Z _H and Z _DR is 0.8 and 0.1 dB, respectively. A similar evaluation is done in the rain medium at larger ranges with the antenna pointing at low elevation angles. The long time stability of the absolute reflectivity calibration is also established by radar-rain gage inter-comparison over almost 200 hours of precipitation data collected during nearly two years.