Numerous rare and new mineral species are synthesized during the process of pyrometamorphism (Gross, 1977; Chesnokov et al., 1987; Chesnokov and Shcherbakova, 1991; Chesnokov, 1999), including silicooxides, chloride-, fluoride, and sulfate-silicates, carbonate-sulfides, chloride-oxides, etc. Having made sense of numerous findings of compounds of this type, Chesnokov (1999) set forth the concept of the crystallochemical transition at extreme temperatures attaining 1200–1450°C in pyrogenic systems. First of all, intertype transitions (oxygen-bearing-oxygen-free) and interclass transitions (chloride-silicate, carbonate-sulfide, chlorideoxide) are realized. The specificity of pyrometamorphic mineral assemblages consists in the abundance of silicates with additional anions (F⁻, Cl⁻, (CO₃)²⁻) (Sokol et al., 2005). Minerals of the ellestadite group Ca₁₀(SiO₄)_{3 − x} (SO₄)_{3 − x} (PO₄)_2x (OH,F,Cl)₂ are a spectacular example of these features. In the general case, they are silicate-sulfate-phosphate-hydroxide-chlorides-fluorides. The detailed description of these minerals based on the study of the original collection of pyrometamorphic minerals is presented in this paper.