We analyse the kinetics of CO
2 and methane hydrate formation. The characteristic formation times are associated with different steps of the formation process.
Conditions for minimising these rate times are identified while maintaining a regime where CO
2 hydrate is formed and methane remains predominantly gaseous. This involves a rapid pressurisation routine and accesses points
well above the phase boundary in order to enable faster kinetics. Conditions for optimising rates and times, to obtain maximum
CO
2 uptake with respect to CH
4, were identified as (1) stirring faster than 1,000 rpm, (2) rapid pressurisation to a partial pressure of around 50 bar for
CO
2 and (3) re-use of contaminated as opposed to fresh water.
Keywords Natural gas - Contamination - CO2
- Hydrates - Kinetics