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Abstract

1.  By replacing the halogen in thegamma- andbeta-iodopyridine N-oxides by the 3-methyl-3-hydroxybutynyl group we synthesized the N-oxides of tertiary pyridinylacetylenic alcohols. The alcohols were converted to the corresponding ethynylpyridine N-oxides by cleavage by the reverse Favorskii reaction.
2.  agr-Iodopyridine was condensed with a number of terminal acetylenic compounds.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1168–1170, May, 1973.

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