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Abstract

We report the short- and long-range behavior of the inner r < (r) \rho_<(r) and outer $ \rho_>(r) $ \rho_>(r) densities, which result from a rigorous partitioning of the spherically averaged one-electron density r(r) \rho(r) in many-electron atoms. It is found that for a small r, r < (r) \rho_<(r) has one-electron nature but $ \rho_>(r) $ \rho_>(r) has two-electron nature. For a large r, however, the opposite is true.

Keywords  Short-range behavior - Long-range behavior - Inner density - Outer density

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