Sample dependence of anisotropy and restriction of electron-spin diffusion in the quasi-one dimensional organic conductor (fluoranthene)2\mathsf{_2} PF6\mathsf{_6}

T. Wokrina, J. Gmeiner, N. Kaplan and E. Dormann

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Abstract

As-grown and proton-irradiation damaged crystals of the quasi-one dimensional organic conductor (fluoranthene)2PF6 are studied by static magnetic field gradient spin echo electron spin resonance. The parallel-to-stack diffusion constant D||D_{\parallel} varies sample dependent by a factor of 50, just like the ratio D||/D^D_{\parallel}/D_{\bot} . The restriction of free diffusive motion of the conduction electron spins of as-grown and microstructured crystals is analyzed.
Received: 20 May 2003, Published online: 2 October 2003
PACS:   76.30.Pk Conduction electrons - 72.15.Lh Relaxation times and mean free paths - 61.72.-y Defects and impurities in crystals, microstructure - 61.80.Jh Ion radiation effects

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